A novel trigonal propeller-shaped hybrid tri-neodymium-polyoxometalate exhibiting single-molecule magnet behavior.
| Author | |
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| Abstract | :
A trigonal propeller-shaped hybrid polyoxometalate (POM) (NH2Me2)3{[Nd(Mo4O13)(DMF)4]3(BTC)2}ยท8DMF (1; BTC = 1,3,5-benzenetricarboxylate) has been synthesized and structurally characterized. The planar {Mo4} segment is tailored from the precursor Lindqvist polyoxoanion [Mo6O19]2- firstly, and plays a key role in the reassembly of 1. Furthermore, the magnetic studies reveal that 1 shows single-molecule magnet (SMM) behavior. |
| Year of Publication | :
2018
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| Journal | :
Dalton transactions (Cambridge, England : 2003)
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| Date Published | :
2018
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| ISSN Number | :
1477-9226
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| URL | :
http://dx.doi.org/10.1039/c7dt04908k
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| DOI | :
10.1039/c7dt04908k
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| Short Title | :
Dalton Trans
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| Download citation |