Geminate and nongeminate recombination of triplet excitons formed by singlet fission.
Author | |
---|---|
Abstract | :
We report the simultaneous observation of geminate and nongeminate triplet-triplet annihilation in a solution-processable small molecule TIPS-tetracene undergoing singlet exciton fission. Using optically detected magnetic resonance, we identify recombination of triplet pairs directly following singlet fission, as well as recombination of triplet excitons undergoing bimolecular triplet-triplet annihilation. We show that the two processes give rise to distinct magnetic resonance spectra, and estimate the interaction between geminate triplet excitons to be 60 neV. |
Year of Publication | :
2014
|
Journal | :
Physical review letters
|
Volume | :
112
|
Issue | :
23
|
Number of Pages | :
238701
|
Date Published | :
2014
|
ISSN Number | :
0031-9007
|
URL | :
https://link.aps.org/abstract/PRL/v112/p238701
|
DOI | :
10.1103/PhysRevLett.112.238701
|
Short Title | :
Phys Rev Lett
|
Download citation |